Lesson plan

Δ18O

In geochemistry, paleoclimatology and paleoceanography δ 18 O or delta-O-18 is a measure of the deviation in ratio of stable isotopes oxygen-18 ( 18 O) and oxygen-16 ( 16 O). It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, and as an indicator of processes that show isotopic fractionation, like methanogenesis. In paleosciences, 18 O: 16 O data from corals, foraminifera and ice cores are used as a proxy for temperature. It is defined as the deviation in "per mil" (‰, parts per thousand) between a sample and a standard: : \delta \ce{^{18}O} = \left( \frac{\left( \frac\ce{^{18}O}\ce{^{16}O} \right)_\mathrm{sample}}{\left( \frac\ce{^{18}O}\ce{^{16}O} \right)_\mathrm{standard}} - 1 \right) \times 1000 ‰ where the standard has a known isotopic composition, such as Vienna Standard Mean Ocean Water (VSMOW). The fractionation can arise from kinetic, equilibrium, or mass-independent fractionation.

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Article summary

In geochemistry, paleoclimatology and paleoceanography δ 18 O or delta-O-18 is a measure of the deviation in ratio of stable isotopes oxygen-18 ( 18 O) and oxygen-16 ( 16 O). It is commonly used as a measure of the temperature of precipitation, as a measure of groundwater/mineral interactions, and as an indicator of processes that show isotopic fractionation, like methanogenesis. In paleosciences, 18 O: 16 O data from corals, foraminifera and ice cores are used as a proxy for temperature. It is defined as the deviation in "per mil" (‰, parts per thousand) between a sample and a standard: : \delta \ce{^{18}O} = \left( \frac{\left( \frac\ce{^{18}O}\ce{^{16}O} \right)_\mathrm{sample}}{\left( \frac\ce{^{18}O}\ce{^{16}O} \right)_\mathrm{standard}} - 1 \right) \times 1000 ‰ where the standard has a known isotopic composition, such as Vienna Standard Mean Ocean Water (VSMOW). The fractionation can arise from kinetic, equilibrium, or mass-independent fractionation.

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Discussion questions

  1. Summarise the article in your own words. Which single claim would you verify first, and why?
  2. Which claim in this article is most likely to be revised as the sources update? How would you check its current status?
  3. If two sources disagreed about one of these facts, what would you need in order to trust one over the other?

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