Lesson plan
BTBP
The bis-triazinyl bipyridines (BTBPs) are a class of chemical compounds which are tetradentate ligands similar in shape to quaterpyridine. The BTBPs are made by the reaction of hydrazine and a 1,2-diketone (such as hexane-3,4-dione) with 6,6'-dicyano-2,2'-bipyridine. The dicyanobipy can be made by reacting 2,2'-bipy with hydrogen peroxide in acetic acid, (followed by the addition of acetone) to form 2,2'-bipyridine-N,N-dioxide. The 2,2'-bipyridine-N,N-dioxide is then converted into the dicyano compound by treatment with potassium cyanide and benzoyl chloride in a mixture of water and THF. The BTBPs were first reported as synthetic intermediates in the synthesis of quaterpyridines by a Diels-Alder reaction of the triazine ring with tributylstannylacetylene or norbornadiene, after the Diels-Alder reaction a series of other reactions cause the adjunct to lose a molecule of nitrogen and a molecule of cyclopentadiene to form the pyridine ring. The BTBPs are related to the BTPs, the BTPs are the bis-triazinyl pyridines which were introduced to solvent extraction by Z. Kolarik. By extending the central part of the BTPs the BTBPs were created.…
Article summary
The bis-triazinyl bipyridines (BTBPs) are a class of chemical compounds which are tetradentate ligands similar in shape to quaterpyridine. The BTBPs are made by the reaction of hydrazine and a 1,2-diketone (such as hexane-3,4-dione) with 6,6'-dicyano-2,2'-bipyridine. The dicyanobipy can be made by reacting 2,2'-bipy with hydrogen peroxide in acetic acid, (followed by the addition of acetone) to form 2,2'-bipyridine-N,N-dioxide. The 2,2'-bipyridine-N,N-dioxide is then converted into the dicyano compound by treatment with potassium cyanide and benzoyl chloride in a mixture of water and THF. The BTBPs were first reported as synthetic intermediates in the synthesis of quaterpyridines by a Diels-Alder reaction of the triazine ring with tributylstannylacetylene or norbornadiene, after the Diels-Alder reaction a series of other reactions cause the adjunct to lose a molecule of nitrogen and a molecule of cyclopentadiene to form the pyridine ring. The BTBPs are related to the BTPs, the BTPs are the bis-triazinyl pyridines which were introduced to solvent extraction by Z. Kolarik. By extending the central part of the BTPs the BTBPs were created.…
Key claims
No claims recorded.
Discussion questions
- Summarise the article in your own words. Which single claim would you verify first, and why?
- Which claim in this article is most likely to be revised as the sources update? How would you check its current status?
- If two sources disagreed about one of these facts, what would you need in order to trust one over the other?
Bibliography
No sources recorded.
Key claims and bibliography are generated from the same tracked claims and sources as the article page.