Gallane

Gallane, also systematically named trihydridogallium, is an inorganic compound of gallium with the chemical formula (also written as ). It is a photosensitive, colourless gas that cannot be concentrated in pure form. Gallane is both the simplest member of the gallanes, and the prototype of the monogallanes. It has no economic uses, and is only intentionally produced for academic reasons. It has been detected as a transient species in the gas phase; also at low temperature (3.5 K) following the reaction of laser ablated gallium atoms and dihydrogen, and more recently in an argon matrix doped with vapour over solid digallane, Ga 2 H 6 .

Gallane, also systematically named trihydridogallium, is an inorganic compound of gallium with the chemical formula (also written as ). It is a photosensitive, colourless gas that cannot be concentrated in pure form. Gallane is both the simplest member of the gallanes, and the prototype of the monogallanes. It has no economic uses, and is only intentionally produced for academic reasons. It has been detected as a transient species in the gas phase; also at low temperature (3.5 K) following the reaction of laser ablated gallium atoms and dihydrogen, and more recently in an argon matrix doped with vapour over solid digallane, Ga 2 H 6 . ==Structure of monomeric GaH 3 == IR spectroscopic studies indicate that monomeric GaH 3 has a trigonal planar structure. Theoretical Ga-H bond lengths have been calculated as being in the range 155.7 pm to 158.7 pm. Monomeric GaH 3 dimerises in the vapor phase to form Ga 2 H 6 , digallane(6) and the enthalpy change associated with the gas phase dissociation reaction Ga 2 H 6 → 2GaH 3 has been experimentally estimated as 59 ± 16 kJ mol −1 . ===GaH 3 adducts=== The production of adducts can proceed via the direct reaction of digallane(6) or more often due to the thermal fragility of digallane(6) (which decomposes to gallium metal and hydrogen above −20 °C) using a tetrahydridogallate salt as a starting point (e.g. LiGaH 4 ) or alternatively via ligand displacement from an existing adduct. Examples are: Ga 2 H 6 + 2 NMe 3 → (NMe 3 ) 2 ·GaH 3 (−95°C) LiGaH 4 + Me 3 NHCl → LiCl + H 2 + Me 3 N·GaH 3 Me 2 NH + Me 3 N·GaH 3 → Me 2 NH·GaH 3 + Me 3 N Many adducts have been prepared. There are a number of typical structures with neutral adducts (L = monodentate ligand, L-L is bidentate): L.GaH 3 (1:1 complex with monodentate ligand giving 4 coordinate gallium) L 2 ·GaH 3 (2:1 complex with monodentate ligand giving 5 coordinate gallium) H 3 Ga·L-L·GaH 3 (1:2 complex with a bidentate ligand with two 4 coordinate gallium atoms) L'H 3 Ga·L-L·GaH 3 L' (complex with monodentate and bidentate ligands with two 5 coordinate gallium atoms) LGaH 2 (μ-H) 2 GaH 2 L ( 2:2 hydrogen bridged complex) (-L-LGaH 3 -) n (1:1 complex with a bidentate ligand forming a polymeric structure) In comparison to alane (AlH 3 ) with similar ligands, gallane tends to adopt lower coordination numbers. Also whilst N donor ligands form stronger bonds to alumane than phosphines the reverse is typically true for gallane. The monomeric structure of Me 3 N . GaH 3 has been confirmed in both the gas and solid phases. In this regard, the 1:1 adduct contrasts with the corresponding alane complex, Me 3 N . AlH 3 which in the solid is dimeric with bridging hydrogen atoms.

Text derived from https://en.wikipedia.org/w/index.php?oldid=1367699855 under CC BY-SA 4.0; modifications have been made.