Lesson plan

Hexanitrogen

Hexanitrogen (diazide, hexaaza-1,2,4,5-tetraene) is an allotrope of nitrogen with the formula N 6 . The six nitrogen atoms are all covalently bonded in a single molecule: two azide units linked to each other. Its stability and structure were theorized in 2016 and its synthesis was reported in 2025. It is stable at cryogenic temperatures. The higher symmetry analogue, the benzene-like cyclic hexazine, has remained only theoretically hypothesized. Its synthesis has been regarded as highly significant, as higher allotropes of nitrogen have potential application as propellants, explosives or energy storage.

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Article summary

Hexanitrogen (diazide, hexaaza-1,2,4,5-tetraene) is an allotrope of nitrogen with the formula N 6 . The six nitrogen atoms are all covalently bonded in a single molecule: two azide units linked to each other. Its stability and structure were theorized in 2016 and its synthesis was reported in 2025. It is stable at cryogenic temperatures. The higher symmetry analogue, the benzene-like cyclic hexazine, has remained only theoretically hypothesized. Its synthesis has been regarded as highly significant, as higher allotropes of nitrogen have potential application as propellants, explosives or energy storage.

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  1. Summarise the article in your own words. Which single claim would you verify first, and why?
  2. Which claim in this article is most likely to be revised as the sources update? How would you check its current status?
  3. If two sources disagreed about one of these facts, what would you need in order to trust one over the other?

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