Lesson plan

Jarzynski equality

The Jarzynski equality (JE) is an equation in statistical mechanics that relates free energy differences between two states and the irreversible work along an ensemble of trajectories joining the same states. It is named after the physicist Christopher Jarzynski (then at the University of Washington and Los Alamos National Laboratory, currently at the University of Maryland) who derived it in 1996. Fundamentally, the Jarzynski equality points to the fact that the fluctuations in the work satisfy certain constraints separately from the average value of the work that occurs in some process.

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Article summary

The Jarzynski equality (JE) is an equation in statistical mechanics that relates free energy differences between two states and the irreversible work along an ensemble of trajectories joining the same states. It is named after the physicist Christopher Jarzynski (then at the University of Washington and Los Alamos National Laboratory, currently at the University of Maryland) who derived it in 1996. Fundamentally, the Jarzynski equality points to the fact that the fluctuations in the work satisfy certain constraints separately from the average value of the work that occurs in some process.

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Discussion questions

  1. Summarise the article in your own words. Which single claim would you verify first, and why?
  2. Which claim in this article is most likely to be revised as the sources update? How would you check its current status?
  3. If two sources disagreed about one of these facts, what would you need in order to trust one over the other?

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