Lesson plan
Kelliphite
Kelliphite is an acronym for the organophosphorus compound 6,6'-[(1,1'-Biphenyl-2,2'-diyl)bis(oxy)]bis[4,8-di-tbutyl-1,2,10,11-tetramethyl]dibenzo[d,f][1,3,2]dioxaphosphepin. This chiral ligand is widely used in asymmetric synthesis. In one example, this ligand is used to form a rhodium complex to catalyze asymmetric hydroformylation of prochiral olefins. It has been shown that high substrate concentrations as well as a wide variety of functional groups are tolerated.
Article summary
Kelliphite is an acronym for the organophosphorus compound 6,6'-[(1,1'-Biphenyl-2,2'-diyl)bis(oxy)]bis[4,8-di-tbutyl-1,2,10,11-tetramethyl]dibenzo[d,f][1,3,2]dioxaphosphepin. This chiral ligand is widely used in asymmetric synthesis. In one example, this ligand is used to form a rhodium complex to catalyze asymmetric hydroformylation of prochiral olefins. It has been shown that high substrate concentrations as well as a wide variety of functional groups are tolerated.
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Discussion questions
- Summarise the article in your own words. Which single claim would you verify first, and why?
- Which claim in this article is most likely to be revised as the sources update? How would you check its current status?
- If two sources disagreed about one of these facts, what would you need in order to trust one over the other?
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